Solvothermal Synthesis, Crystal Structure, and Properties of the First Zinc Containing Thioantimonate(III) [Zn(tren)]2Sb4S8·0.75 H2O
✍ Scribed by Michael Schaefer; Christian Näther; Wolfgang Bensch
- Publisher
- Springer Vienna
- Year
- 2004
- Tongue
- English
- Weight
- 188 KB
- Volume
- 135
- Category
- Article
- ISSN
- 0026-9247
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Five new thioantimonates have been synthesized in the presence of organic amines under solvothermal conditions and their structures determined by single-crystal X-ray diffraction. All of the compounds are layered and contain antimony-sulphide anions of stoichiometry [Sb 4 S 7 ] 2À , but the structur
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The novel thioantimonate(III) [Fe(C 4 H 13 N 3 ) 2 ]Sb 6 S 10 • 0.5 H 2 O was synthesised under mild hydrothermal conditions by allowing elemental Fe, Sb, and S to react in a 50% diethylenetriamine (dien) solution. The compound crystallises in the monoclinic space group C2/c with a = 33.789(3), b =