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The structure and stereochemistry of rimuene

✍ Scribed by R.E. Corbett; S.G. Wyllie

Publisher: Elsevier Science
Year: 1964
Tongue: French
Weight: 222 KB
Volume: 5
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)89471-5

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✦ Synopsis

The diterpene hydrocarbon rimuene first isolated by McDowall and Findlay (I) from the essential oil of Dacrydium cupreseinum (rimu) has been the subject of a number of structural investigations (2,3,4,5,6). The proposed structure (3,4) has been shown by recent synthetic work (7) to be incorrect. Earlier investigations had established that rlmuene ha8 the usual perhydrophenanthrene skeleton with a genimal dimethyl group at C(4), vinyl and methyl group8 at C(13) and a triaubstituted double bona.

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