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The constitution and stereochemistry of rimuene

✍ Scribed by J.D. Connolly; R. McCrindle; R.D.H. Murray; K.H. Overton

Publisher: Elsevier Science
Year: 1964
Tongue: French
Weight: 28 KB
Volume: 5
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)75144-6

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The constitution of rimuene has been the subject of protracted controversy in recent years and indeed represents an outstanding unsolved problem in diterpene chemistry. Our recent interest in the constituents of Erythroxylon monogyuum (1) has caused us to re-e xamine the published evidence on rimue

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The diterpene hydrocarbon rimuene first isolated by McDowall and Findlay (I) from the essential oil of Dacrydium cupreseinum (rimu) has been the subject of a number of structural investigations (2,3,4,5,6). The proposed structure (3,4) has been shown by recent synthetic work (7) to be incorrect. Ear

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