The structure and stability of S2F10 and S2F11 and their anions
β Scribed by G.L. Gutsev
- Book ID
- 103667600
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 576 KB
- Volume
- 158
- Category
- Article
- ISSN
- 0301-0104
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π SIMILAR VOLUMES
Equilibrium geometries of PFs (D& PF; (Oh) and PIF: (Did and Dbb) were determined on the SCF level employing extended basis sets. Total energies of anions and the corresponding neutral systems were calculated. The anions PF; and P2 FL are stable with respect to dissociation into PFs+ F-(92.6 kcal/mo
Data on the kinetics of S,F,, pyrolysis, which gives SF, + SF, , have been reinterpreted to give a value for the equilibrium constant of S,FIo SF, + SF, . This, together with statistical estimates of the entropy and heat capacity of S,F,, , can be used to give for this reaction values of AH,.,, = 19