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The structure and stability of S2F10 and S2F11 and their anions

✍ Scribed by G.L. Gutsev


Book ID
103667600
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
576 KB
Volume
158
Category
Article
ISSN
0301-0104

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πŸ“œ SIMILAR VOLUMES


Ab initio study of structure, stability
✍ Christoph KΓΆlmel; Gottfried Palm; Reinhart Ahlrichs; Michael BΓ€r; Alexander I. B πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 English βš– 464 KB

Equilibrium geometries of PFs (D& PF; (Oh) and PIF: (Did and Dbb) were determined on the SCF level employing extended basis sets. Total energies of anions and the corresponding neutral systems were calculated. The anions PF; and P2 FL are stable with respect to dissociation into PFs+ F-(92.6 kcal/mo

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The kinetics and thermochemistry of S2F1
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Data on the kinetics of S,F,, pyrolysis, which gives SF, + SF, , have been reinterpreted to give a value for the equilibrium constant of S,FIo SF, + SF, . This, together with statistical estimates of the entropy and heat capacity of S,F,, , can be used to give for this reaction values of AH,.,, = 19