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The structural dependence of geminal and vicinal CC coupling constants

✍ Scribed by Jung-hyuck Cho; Martin Klessinger; Ute Tecklenborg; Konrad Wilhelm

Book ID: 102949991
Publisher: John Wiley and Sons
Year: 1985
Tongue: English
Weight: 532 KB
Volume: 23
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260230209

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✦ Synopsis

Abstract

CC coupling constants of ten bicyclic hydrocarbons and ten cyclic ethers or carbonyl compounds were determined from the satellites of broad band decoupled spectra or from INADEQUATE measurements. The influences of valence angles, dihedral angles, hybridization and heterosubstitution on geminal and vicinal CC coupling constants are discussed in terms of the algebraic additivity of the contributions from individual coupling paths within the framework of a multiple path mechanism.

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