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Structural elucidation of disubstituted nortricyclenes through vicinal 13C, 1H coupling constants

✍ Scribed by I. D. Gridnev; I. F. Leshcheva; N. M. Sergeyev; V. A. Chertkov

Book ID
102524864
Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
469 KB
Volume
30
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Vicinal ^13^C, ^1^H coupling constants were used to establish the configuration of a 3,5‐disubstituted notricyclene. The assignment procedure is supported by independent measurements of ^13^C, ^2^H coupling constants in 3‐ deuterionortricyclene and confirmed by ^1^H, ^1^H NOE data for exo‐3‐N‐acetylamino‐exo‐5‐pivaloylnortricyclene.

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