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The stobbe condensation of 3,4-disubstituted acetophenones with diethyl succinate

✍ Scribed by El-Newaihy, M. F.; El-Hashash, M. A.

Book ID
120194307
Publisher
The Royal Society of Chemistry
Year
1971
Tongue
English
Weight
393 KB
Category
Article
ISSN
0022-4952

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γγ-Disubstituted Itaconic Acids. Part 1.
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## Abstract Arylnaphthyl ketones condense with diethyl succinate yielding the stereoisomeric half‐esters **2a–2d** which were subjected to a series of reactions leading to 1‐phenylphenanthrene and 1,1′‐binaphthyl derivatives. (__E__)‐3‐Ethoxycarbonyl‐4‐(4‐methoxynaphth‐1‐yl)‐4‐arylbut‐3‐enoic acids

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**Eine neue Esterkomponente in der Stobbe‐Kondensation. I. Kondensation einiger aromatischer Aldehyde mit Diethyl‐β,β‐dimethylglutarat** Kondensation von Benzaldehyd und p‐Anisaldehyd mit Diethyl‐β,β‐dimethylglutarat in Gegenwart von Natriumhydrid ergibt die kristallinen (Z)‐Halbester (**1a** und *