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The Stimulated Raman Spectrum of Cyanogen

✍ Scribed by Dionisio Bermejo; Rafael Escribano; Julio Santos

Publisher: Elsevier Science
Year: 1997
Tongue: English
Weight: 365 KB
Volume: 186
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.1997.7417

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✦ Synopsis

The Raman spectrum of cyanogen 12 C 2 14 N 2 has been investigated at nearly Doppler resolution by means of the Stimulated Raman technique. The regions around the Q branches of the n 1 (2330 cm 01 ) and n 2 (845 cm 01 ) vibrations have been recorded. Besides the fundamentals, hot bands arising from £ 5 Å 1, £ 5 Å 2, and £ 4 Å 1 have been observed. The spectra have been analyzed, and rotational constants for the excited states have been obtained. Computer simulations of the Raman contours have been carried out as a test of the assignments.

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