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High-Resolution Stimulated Raman Spectrum of F2

✍ Scribed by R.Z. Martinez; D. Bermejo; J. Santos; P. Cancio

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 322 KB
Volume: 168
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.1994.1283

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✦ Synopsis

The high-resolution stimulated Raman spectrum of (F_{2}) has been recorded with a quasi (\mathrm{cw}) technique. (Q) branches of the fundamental and first hot band have been fully resolved. Forty-one transitions of the (Q) branch of the fundamental up to (J=43) have been measured, in addition to 21 transitions of the (O) and (S) branches of this band. Twenty-one transitions of the (Q) branch of the first hot band up to (J=27) have also been measured. From the analysis of these data more accurate set of molecular parameters for the (v=0, v=1), and (v=2) states of this molecule has been derived. From our data and some previous fluorescence data a new set of equilibrium parameters is also proposed. (c) 1994 Academic Press, Inc.

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