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The Steric Course of Hydration of 1,2-Dimethylcyclohexene

✍ Scribed by COLLINS, CAROL H.; HAMMOND, GEORGE S.


Book ID
126888294
Publisher
American Chemical Society
Year
1960
Tongue
English
Weight
360 KB
Volume
25
Category
Article
ISSN
0022-3263

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Six-membered ring ketones such as 4 butyl-cyclohexanone, I, are attacked by nucleophiles (e.g., Grignard reagents or metal hydrides) from two different sites giving rise to products E with an equatorial OH group, and A with.an axial OH group. The ratio of the amounts the rate constants 1, 2) have re