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The stereoselective total synthesis of PF1163A

โœ Scribed by Kumar, Harish; Reddy, A. Srinivas; Reddy, B.V. Subba


Book ID
121725197
Publisher
Elsevier Science
Year
2014
Tongue
French
Weight
611 KB
Volume
55
Category
Article
ISSN
0040-4039

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A stereoselective total synthesis of (โˆ’)
โœ Jiong Chen; John N. Marx ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 182 KB

A new synthesis of (-)-rishitin (1) is reported, starting with chiral pool molecules. The crucial step is a stereo,selective vinyl radical eyelization, which gives a 10:1 ratio of 21 to 22.