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The Stereochemistry of Vicinal Hydride Shift in the 3-Methyl-2-norbornyl Cation. Evidence for the Nonclassical Structure 1

โœ Scribed by Berson, Jerome A.; Hammons, James H.; McRowe, Arthur W.; Bergman, Robert G.; Remanick, Allen; Houston, Donald


Book ID
126902281
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
271 KB
Volume
87
Category
Article
ISSN
0002-7863

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Vinyl cations, 22 a 1,2-hydride shift in
โœ Klaus-Peter Jรคckel; Michael Hanack ๐Ÿ“‚ Article ๐Ÿ“… 1975 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 137 KB

Recently we reprted about the first example of a 1.2-hydride shift durmg the generation of a vrnyl cation, a process well known for trlsubstituted car&mum ions 2) :Thls was obsermildurlng the solvolys~s of cls-and trans-3-cyclop~l-2-propen-2-yl-trifl~~~esulfo~~(tnflate)3! --The 1.2-hydride shLft was