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The Stereochemistry of the Hunsdiecker Reaction on a Cyclopropane Ring 1

✍ Scribed by Applequist, Douglas E.; Peterson, Alan H.

Book ID
118060878
Publisher
American Chemical Society
Year
1960
Tongue
English
Weight
741 KB
Volume
82
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

The Stereochemistry of Carbenoid Cyclopr
The Stereochemistry of Carbenoid Cyclopropanation Reactions
✍ Hans Christian Stiasny; Reinhard W. Hoffmann πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 670 KB

The stereochemical course of the intramolecular carbenoid cyclopropanation reaction has been studied for the epimeric carbenoids 12a and 12b. In these reactions the terl-butyldimethylsilyloxy substituent serves as an internal stereochemical reference point. It was found that 12b cyclizes rapidly at