Recent Developments in the Stereochemistry of Cyclopropane Ring Opening
β Scribed by Prof. Dr. S. Sarel; Dr. J. Yovell; Dr. M. Sarel-Imber
- Publisher
- John Wiley and Sons
- Year
- 1968
- Tongue
- English
- Weight
- 983 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The reported instances of inversion of configuration in the acid-catalyzed opening of cyclopropane rings are rare.2 The recent report' of exclusive inversion in the hydrogen chloride promoted opening of a fused cyclopropane ring prompts us to amplify our previous observations4 of a similarly strikin
## Abstract From the O~2~βdependence of the trapping rate of 1,1βdifluoroβ2,3βdiphenylcyclopropane in supercritical CO~2~ in the temperature range 110β180Β°C and the rates of its geometrical isomerization and racemization of the __trans__βisomer, the energy profile for the geometrical isomerization