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The stereochemistry of oxymercuration of 5-norbornene-2-endo-carboxylic acid

✍ Scribed by Frederick R. Jensen; John J. Miller

Publisher
Elsevier Science
Year
1966
Tongue
French
Weight
238 KB
Volume
7
Category
Article
ISSN
0040-4039

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## Abstract Mass spectrometrical and ^1^H‐NMR.‐analyses of the __exo__‐5‐norbornen‐2‐yl acetate, formed by acetolysis of __endo__‐5‐norbornen‐2‐yl‐2‐__exo__‐d brosylate, demonstrate that the deuterium initially on C(2) migrates partially (30%) onto C(1) (mechanism Ia or Ib). No deuterium could be d