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Tetra­methyl­pyrazine–endo-norbornene-cis-5,6-di­carboxyl­ic acid (1/2)

✍ Scribed by Hu, Mao-Lin ;Jin, Zhi-Min ;Zhao, Ya-Juan ;Chen, Di-Mei ;Wang, Shun ;Cai, Xiao-Qing


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
250 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title complex, 2C 9 H 10 O 4 ÁC 8 H 12 N 2 , there is an inversion centre at the centre of the 2,3,5,6-tetramethylpyrazine molecule, which is linked to two endo-norbornene-cis-5,6-dicarboxylic acid molecules via O-HÁ Á ÁN hydrogen bonds. In the crystal structure, O-HÁ Á ÁO and O-HÁ Á ÁN hydrogen bonds propagate a one-dimensional zigzag chain, which is extended into layers when combined with longer C-HÁ Á ÁO hydrogen bonds.


📜 SIMILAR VOLUMES


2-Norbornene-exo,endo-5,6-di­carboxyl­ic
✍ Batsanov, Andrei S. ;Hesselink, Joanna L. 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 167 KB

The crystal structure of the title compound, C 9 H 10 O 4 , contains in®nite hydrogen-bonded chains of molecules. The norbornene skeleton is slightly twisted.

2-Norbornene-exo-cis-5,6-di­carboxyl­ic
✍ Batsanov, Andrei S. ;Hesselink, Joanna L. 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 334 KB

Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.003 A Ê Disorder in main residue R factor = 0.049 wR factor = 0.102 Data-to-parameter ratio = 12.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Tetra­hydro-2,6,6-tri­methyl-1,4-pyran-2
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✍ Dale, Sophie H. ;Elsegood, Mark R. J. 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 165 KB

The title compound, C 10 H 6 O 8 .2C 2 H 6 OS, one of the few known examples of the cocrystallization of pyromellitic acid with common organic solvents, has been previously analysed by single-crystal X-ray diffraction at 296 K [Jin, Pan, Shen, Li & Hu (2003). Acta Cryst. C59, o205±o206]. We present

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.006 A Ê R factor = 0.055 wR factor = 0.167 Data-to-parameter ratio = 12.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

N,N′-Bis(2-carboxy­ethyl)-1,4,5,8-naphth
✍ Fallon, Gary D. ;Langford, Steven J. ;Lee, Marcia A.-P. 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 164 KB

In the title compound, C 20 H 14 N 2 O 8 Á2C 3 H 7 NO, the essentially planar C 20 H 14 N 2 O 8 molecule is centrosymmetric and is hydrogen bonded via the carboxylic acid H atoms to the aldehyde O atom of the dimethylformamide molecules.