The crystal structure of the title compound, C 9 H 10 O 4 , contains in®nite hydrogen-bonded chains of molecules. The norbornene skeleton is slightly twisted.
Tetramethylpyrazine–endo-norbornene-cis-5,6-dicarboxylic acid (1/2)
✍ Scribed by Hu, Mao-Lin ;Jin, Zhi-Min ;Zhao, Ya-Juan ;Chen, Di-Mei ;Wang, Shun ;Cai, Xiao-Qing
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 250 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title complex, 2C 9 H 10 O 4 ÁC 8 H 12 N 2 , there is an inversion centre at the centre of the 2,3,5,6-tetramethylpyrazine molecule, which is linked to two endo-norbornene-cis-5,6-dicarboxylic acid molecules via O-HÁ Á ÁN hydrogen bonds. In the crystal structure, O-HÁ Á ÁO and O-HÁ Á ÁN hydrogen bonds propagate a one-dimensional zigzag chain, which is extended into layers when combined with longer C-HÁ Á ÁO hydrogen bonds.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.003 A Ê Disorder in main residue R factor = 0.049 wR factor = 0.102 Data-to-parameter ratio = 12.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, C 10 H 16 O 5 , the carboxylate group at the C-2 position is axial, but that at C-5 is equatorial. These carboxylate groups form hydrogen-bonded rings [average OÁ Á ÁO H distance = 2.64 (1) A Ê ] across the inversion centers at ( 1 2 , 0, 0) and ( 1 2 , 1 2 , 1 2 ), respective
The title compound, C 10 H 6 O 8 .2C 2 H 6 OS, one of the few known examples of the cocrystallization of pyromellitic acid with common organic solvents, has been previously analysed by single-crystal X-ray diffraction at 296 K [Jin, Pan, Shen, Li & Hu (2003). Acta Cryst. C59, o205±o206]. We present
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