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The stereochemistry of metal catalysed hydrogen cyanide addition to alkenes

✍ Scribed by W.Roy Jackson; Craig G. Lovel

Publisher: Elsevier Science
Year: 1982
Tongue: French
Weight: 215 KB
Volume: 23
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)87174-9

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✦ Synopsis

Reactions of both terminal and cyclic alkenes have been shown to occur in a stereospecifically cis -manner with deuterium cyanide when a catalyst system based on -Pd(DIOP), was used. Reactions of cyclohexene give only the products of equatorial cyanide incorporation.

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