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Addition of Nitriles to Metal Sulfides: Possible Insight into the Metal Sulfide Catalyzed Hydrogenation of Nitriles and Dinitrogen

✍ Scribed by Jonathan T. Goodman; Prof. Thomas B. Rauchfuss


Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
409 KB
Volume
36
Category
Article
ISSN
0044-8249

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## Abstract The mild oxidation of sulfides to sulfoxides with an aqueous solution of H~2~O~2~ (35%) catalyzed by __in situ__ generated dodecyl hydrogen sulfate as BrΓΈnsted acid surfactant in the absence of any organic co‐solvents and under metal‐free conditions is described. The method shows high c