Butadiene dianion equivalent, 1,Caddition / Metallocene template, bent / Enamine, primary, stable / Metallacycles, nine-membered, chiral / Zirconocene (q4-Butadiene)zirconocene adds one equivalent of benzonitrile to form the five-membered azazirconacyclopentene derivative 9, which contains an NH gro
Addition of Nitriles to Metal Sulfides: Possible Insight into the Metal Sulfide Catalyzed Hydrogenation of Nitriles and Dinitrogen
β Scribed by Jonathan T. Goodman; Prof. Thomas B. Rauchfuss
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 409 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0044-8249
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## Abstract The mild oxidation of sulfides to sulfoxides with an aqueous solution of H~2~O~2~ (35%) catalyzed by __in situ__ generated dodecyl hydrogen sulfate as BrΓΈnsted acid surfactant in the absence of any organic coβsolvents and under metalβfree conditions is described. The method shows high c