The reaction of 3-phenylpropen-l-y1 magnesium chloride with benzaldehyde gave a mixture (7:3) of homoallylic alcohols (1) and (2) the relative configuration of which was determined from an X-ray analysis of the major epoxide formed by m-chloroperbenzoic oxidation of alcohol (1).
The stereochemistry of forward and reverse reactions in the addition of hydridocobaloxime to (E)-1-phenylpropene
✍ Scribed by Sylvie Derenne; Alain Gaudemer; Michael D. Johnson
- Book ID
- 103221722
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 684 KB
- Volume
- 322
- Category
- Article
- ISSN
- 0022-328X
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