✦ LIBER ✦
The stereochemistry of the product homoallylic alcohols from a modified grignard reaction of 3-phenylpropen-1-yl chloride and benzaldehyde.
✍ Scribed by James M. Coxon; Gregory W. Simpson; Peter J. Steel; V.Craige Trenerry
- Book ID
- 104217123
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- French
- Weight
- 123 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
The reaction of 3-phenylpropen-l-y1 magnesium chloride with benzaldehyde gave a mixture (7:3) of homoallylic alcohols (1) and (2) the relative configuration of which was determined from an X-ray analysis of the major epoxide formed by m-chloroperbenzoic oxidation of alcohol (1).