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The stereochemical consequences of the addition of chlorocarbene to norbornene

✍ Scribed by C.W. Jefford; R. Medary

Publisher
Elsevier Science
Year
1966
Tongue
French
Weight
286 KB
Volume
7
Category
Article
ISSN
0040-4039

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✦ Synopsis

tR.!l. 1 (Xoooivod 5 Maroh 1966) lho addition of dihmlooarbonoa to norbornonm proooodm xtorooapxoi+ioxlly to form thx a-oyolopropmo adduot [II whioh can undergo thxrml rxarrangront to xxo-3,4-dihxlobioyolo C3.2.11 octane-2 [III '. -Y l X -Cl, Br Whatwar thm nmturo of thm intxrmadixtm or transition l tatm in the roxrronl;xmmnt, it is olmxr that during the oonvaraion of I to II, Cg movoa in thx rndo dirmotion and Y milratar to ths l o C4 position, -

πŸ“œ SIMILAR VOLUMES

The addition of bromofluorocarbene to no
The addition of bromofluorocarbene to norbornene
✍ C.W. Jefford; D.T. Hill πŸ“‚ Article πŸ“… 1969 πŸ› Elsevier Science 🌐 French βš– 196 KB

To date little has been reported of the generation and addition of bromofluorocarbene to olefins. 4 Accordingly we now report our preliminary results on the basic hydrolysis of dibromofluoromethane as a previous work, norbomene Dibromofluoromethane convenient source of bromofluorocarbene.