The dibromocarbene or bromofluorocarbene addition to substituted allyldisilanes afforded instable gemdibromocyclopropanes or a gem-bromofluorocyclopropane, respectively. These gem-bromohalogenocyclopropanes undergo a spontaneous ring opening at room temperature to give halogenated dienylsilanes or b
The addition of bromofluorocarbene to norbornene
โ Scribed by C.W. Jefford; D.T. Hill
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 196 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
To date little has been reported of the generation and addition of bromofluorocarbene to olefins.
4 Accordingly we now report our preliminary results on the basic hydrolysis of dibromofluoromethane as a previous work, norbomene Dibromofluoromethane convenient source of bromofluorocarbene.
๐ SIMILAR VOLUMES
tR.!l. 1 (Xoooivod 5 Maroh 1966) lho addition of dihmlooarbonoa to norbornonm proooodm xtorooapxoi+ioxlly to form thx a-oyolopropmo adduot [II whioh can undergo thxrml rxarrangront to xxo-3,4-dihxlobioyolo C3.2.11 octane-2 [III '. -Y l X -Cl, Br Whatwar thm nmturo of thm intxrmadixtm or transition l