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The state of water and the nature of ion clusters in crosslinked proton conducting membranes of styrene grafted and sulfonated poly(vinylidene fluoride)

✍ Scribed by Elomaa, Matti; Hietala, Sami; Paronen, Mikael; Walsby, Nadia; Jokela, Kaija; Serimaa, Ritva; Torkkeli, Mika; Lehtinen, Tero; Sundholm, Göran; Sundholm, Franciska

Book ID
118066772
Publisher
Royal Society of Chemistry
Year
2000
Tongue
English
Weight
134 KB
Volume
10
Category
Article
ISSN
0959-9428

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A series of proton exchange membranes have been prepared by the preirradiation grafting method. Styrene was grafted onto a matrix of poly(vinylidene fluoride) (PVDF) after electron beam irradiation. Part of the samples was crosslinked with divinylbenzene (DVB) or bis(vinylphenyl)ethane (BVPE). Subse

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Crosslinked proton exchange membranes were prepared by electron beam grafting of styrene with divinylbenzene, DVB, or bis(vinyl phenyl)ethane, BVPE, on to poly-(vinylidene fluoride), PVDF, followed by sulfonation. The area and thickness increase, crystallinity and mechanical properties of the membra