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The standard enthalpies of formation of 2-methylbiphenyl and diphenylmethane

✍ Scribed by W.V. Steele; R.D. Chirico; N.K. Smith

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 346 KB
Volume: 27
Category: Article
ISSN: 0021-9614
DOI: 10.1006/jcht.1995.0068

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✦ Synopsis

Measurements of the energies of combustion are reported for 2-methylbiphenyl (Chemical Abstracts registry number [643-58-3]), and diphenylmethane (registry number [101-81-5]). Standard enthalpies of combustion and formation in the condensed state are derived for both compounds. Standard enthalpies of vaporization at 298.15 K are reported for both compounds and the corresponding ideal-gas standard enthalpies of formation derived. The results are compared with literature values and discrepancies arising from the use of values for diphenylmethane from a comprehensive compilation are clarified.

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