The derived standard molar enthalpies of formation in the gaseous state are shown to fit a group additivity scheme.
The standard molar enthalpies of formation of some alkyladamantanes
β Scribed by S.V. Melkhanova; ; S.M. Pimenova; ; V.P. Kolesov; ; A.A. Pimerzin; ; V.S. Sarkisova
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 114 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0021-9614
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β¦ Synopsis
The standard massic energies of combustion of three alkyl-derivative of adamantane were measured at T = 298.15 K by static-bomb combustion calorimetry. The standard molar enthalpies of formation in the liquid and gaseous states were obtained from these data. The enthalpies of some reactions of isomerization were calculated from the equilibrium study and compared with the results of calorimetric measurements.
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