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The Solvolysis of the Methyl 3-Tosyloxycyclohexanecarboxylates

✍ Scribed by Noyce, Donald S.; Weingarten, H. I.


Book ID
126993756
Publisher
American Chemical Society
Year
1957
Tongue
English
Weight
256 KB
Volume
79
Category
Article
ISSN
0002-7863

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Neighboring sulfur participation in the
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As shown by kinetic and product analysis, the solvolysis of7 and 8 in m includes several competitive reactions, one of them being neighbofing sulfur participation and formation of intermediate cyclic sulfonium cation. Recently we have demonstrated' the absence of r-or n-participation in solvolysis o