𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The solvent-jump relaxation method using continuous flow

✍ Scribed by Z. A. Schelly; M. M. Wong

Book ID
102444958
Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
240 KB
Volume
6
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

A step perturbation (concentration‐jump or solvent‐jump) relaxation method is described for studying the rates of fast reactions, using nontransient observation in a steadystate flow system. Therelaxation time is determined from a single measurement of an integrated relaxation amplitude. Remeasurement of the rate of dimerization of aqueous rhodamine B is reported.

πŸ“œ SIMILAR VOLUMES

Thermodynamic theory of the solvent-jump
Thermodynamic theory of the solvent-jump relaxation method. Coupled equilibria[1]
✍ Z.A. Schelly; D.Y. Chao πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science βš– 561 KB

The thermodynamic properties of an unrestricted number of chemically coupled equilibria in solvent-jump relaxation experiments are described. An overall mean relaxation amplitude A<, if defined, for which an expression is derived as a function of the dilution ratio, the overall equilibrium constants