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Thermodynamic theory of the solvent-jump relaxation method. Coupled equilibria[1]

✍ Scribed by Z.A. Schelly; D.Y. Chao

Book ID
103896518
Publisher
Elsevier Science
Year
1979
Weight
561 KB
Volume
14
Category
Article
ISSN
0378-4487

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✦ Synopsis

The thermodynamic properties of an unrestricted number of chemically coupled equilibria in solvent-jump relaxation experiments are described. An overall mean relaxation amplitude A<, if defined, for which an expression is derived as a function of the dilution ratio, the overall equilibrium constants in the initial and final media of given dielectric constants, as well as the stoichiometric coefficients, activity coefficients, mole numbers, and charges of the species present in the coupled system. In the limit of only one reaction being present, the final equation reduces to an expression obtainable for a single uncoupled equilibrium. The possibility of using A[, in mechanistic decision making is discussed.

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