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The solvent effect on the electronegativity and hardness of bonded atoms

✍ Scribed by Józef Lipiński; Ludwik Komorowski

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
343 KB
Volume
262
Category
Article
ISSN
0009-2614

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✦ Synopsis

The role of solvent interactions in modifying the electronegativity (X) and hardness (r/) of bonded atoms has been studied. The simple virtual charge model of a homogeneous polar medium was chosen for the description of the solvent properties. Molecular X and 77 indices show minor dependences on the solvent polarity. The hardness of ions decreases with increasing solvent polarity whereas the electronegativity index decreases for cations and increases for anions.

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