𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The solvent effect and the structural effect of halides on the quaternization Et3N+RX→Et3RNX

✍ Scribed by Ten-Tsai Wang; Qun-Ling Iou


Book ID
104427078
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
208 KB
Volume
87
Category
Article
ISSN
1385-8947

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


O=P(i-PrNCH2CH2)3NCH3+: Novel effect of
✍ Xiaodong Liu; Brad Logsdon; Robert A. Jacobson; John G. Verkade 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 173 KB 👁 1 views

The title cation features the longest distance between the bridgehead atoms (3.56 A ˚) so far recorded for phosphatrane cages despite a nontetrahedral CN brigehead C angle (ϳ114Њ). The 70.8Њ N bridgehead CCN torsion angles in the bridging moieties produce a substantial twist along the C 3 axis of th

Solvent and Ligand Effects on the Struct
✍ Philipp Gruene; Claudia Trage; Detlef Schröder; Helmut Schwarz 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 135 KB 👁 2 views

## Abstract The effects of the oxidation state, the ligand, and the solvent on structures and energetics of cationic iron complexes are investigated by means of electrospray‐ionization mass spectrometry. Insights into the potential‐energy surfaces of FeX^+^, FeX~2~^+^, and XFe(OCH~3~)^+^ ions (X =

[1,3] and [3,3] rearrangements of 3-amin
✍ Heather K. Dobson; Richard LeBlanc; Hélène Perrier; Corey Stephenson; Teresa R. 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 223 KB

3-Amino-l,5-Hexadienes rearrange under anionic conditions to give a [1,3] product in addition to the [3,3] (Cope) product. With some substrates the regioselectivity of the reaction is strongly influenced by the solvent polarity.