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[1,3] and [3,3] rearrangements of 3-amino-1,5-hexadienes: Solvent effect on the regioselectivity

✍ Scribed by Heather K. Dobson; Richard LeBlanc; Hélène Perrier; Corey Stephenson; Teresa R. Welch; Dwight Macdonald

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 223 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)00455-4

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✦ Synopsis

3-Amino-l,5-Hexadienes rearrange under anionic conditions to give a [1,3] product in addition to the [3,3] (Cope) product. With some substrates the regioselectivity of the reaction is strongly influenced by the solvent polarity.

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## Abstract For Abstract see ChemInform Abstract in Full Text.