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The Solvation Interface is a Determining Factor in Peptide Conformational Preferences

✍ Scribed by Eric J. Sorin; Young Min Rhee; Michael R. Shirts; Vijay S. Pande

Book ID
116662672
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
363 KB
Volume
356
Category
Article
ISSN
0022-2836

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The conformational constraints imposed by 7-1actams in peptides have been studied using valence force field energy calculations and flexible geometry maps. It has been found that while cyclisation restrains the ~u of the lactam, non-bonded interactions contribute to the constraints on ~0 of the lact