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The solid state isotopic exchange reaction between cationic and anionic Co atoms in [Co(H2O)6][Co EDTA]2·4H2O

✍ Scribed by E. Lazzarini; A.L. Fantola Lazzarini


Book ID
115973516
Publisher
Elsevier Science
Year
1975
Weight
392 KB
Volume
37
Category
Article
ISSN
0022-1902

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The Miissbauer spectra of iron and cobalt fluoroborate hexahydrate show a change by a factor of two in the quadrupole interaction near 2%) K and 185 K, respectively, togtther with a sudden drop in resonance fraction. This behaviour is explained as a first order phase transition in which the axial pa