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The SNANRORC mechanism. 27. Occurrence of the SNANRORC mechanism in the amination of 2-substituted purines with potassium amide in liquid ammonia

✍ Scribed by Kos, Nico J.; Van der Plas, Henk C.

Book ID
115501215
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
561 KB
Volume
45
Category
Article
ISSN
0022-3263

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The behaviour of 6- and 8-substituted pu
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## Abstract Reaction of 6‐chloro‐ and 6‐(methylthio)purine with potassium amide in liquid ammonia leads to the formation of adenine. When these aminations are carried out with ^15^N‐labelled potassium amide, the ^15^N label is found to be present in the amino group, proving that these reactions do