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The singlet-state photochemistry of 3-methylene-2,2,5,5-tetramethylcyclohexanone

โœ Scribed by Kenneth G. Hancock; Ronald O. Grider


Book ID
104248289
Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
199 KB
Volume
12
Category
Article
ISSN
0040-4039

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We recently reported the singlet-state photochemical rearrangement of 3-methylene-2,2,5,5-tetramet~lcyclohexanone (1) via a 1,3-sigmatropic acyl shift to 3,3-dimethyl-5-isopropylidenecyclohexanone (g).", However, 17~-acetoyy-4,4-dimetQrl-19-norandrost-5-en-3-one (3)isknown to undergo a triplet-state

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