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Localized photochemical isomerization in a 1,4-bichromophore. The photochemistry of 3-ethylidene-2,2,5,5-tetramethylcyclohexanone anil

โœ Scribed by Hancock, Kenneth G.; Condie, John D.; Barkovich, Anthony J.


Book ID
126240658
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
597 KB
Volume
42
Category
Article
ISSN
0022-3263

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We recently reported the singlet-state photochemical rearrangement of 3-methylene-2,2,5,5-tetramet~lcyclohexanone (1) via a 1,3-sigmatropic acyl shift to 3,3-dimethyl-5-isopropylidenecyclohexanone (g).", However, 17~-acetoyy-4,4-dimetQrl-19-norandrost-5-en-3-one (3)isknown to undergo a triplet-state