3'-D3-Mevalonic acid was required to study triterpenoid biosynthesis. It was synthesized by a simple route in a 24% yield from D3-acetic acid-D. The product was characterized as the crystalline salt: N,N'-dibenzylethylenediammonium bis-(3,5-dihydroxy-3-(D3-methyl)-pentanoate) and was shown by mass s
✦ LIBER ✦
The simple preparation of mevalonic-3′, 4-D Acid and -3′, 4-T Acid
✍ Scribed by Mitsuyoshi Matsuo; Yosihiko Kasida
- Book ID
- 102373903
- Publisher
- John Wiley and Sons
- Year
- 1968
- Tongue
- French
- Weight
- 190 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0022-2135
No coin nor oath required. For personal study only.
✦ Synopsis
Mevalonic-3', 4 -0 acid and -3', 4-T acid were synthesized by using deuterated and tritiated water und the total yield of the labelled M V A was 6.5 %. The specijc activity of the tritiated M V A , which was derived ,from 2.3 g. of tritiated water (250 mCi), MYZS 1.77 mCi.linM.
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Single-crystal X-ray study T = 290 K Mean (C-C) = 0.005 A R factor = 0.069 wR factor = 0.159 Data-to-parameter ratio = 12.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.