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The Significance of Isoselective Temperatures for the Existence of Linear Free-Energy Relationships

✍ Scribed by Prof. Dr. Bernd Giese; Woo-Bung Lee

Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
216 KB
Volume
19
Category
Article
ISSN
0044-8249

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πŸ“œ SIMILAR VOLUMES

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The oxidation of ortho-, meta-, and para-substituted phenols by Quinolinium Dichromate (QDC) to the corresponding Quinones in aqueous acetic acid medium is first-order with respect to [QDC] and [phenol]. There is no effect of added Quinoline on rate. The reaction is acid catalyzed. A medium of low d

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X-ray structure data: triclinic, spacegroup Pi, (I = 12.167(2) A, 6 = 12.921(4) A, c = 15.394(4) .&, a = 314.41(2)". = 97.641(15)", y = 102,17(2)", V = 2087.4 A,, Z = 1, data collected 4.0' 5 28 5 45.0". 4179 unique reflections with F > 6.0u(F), R = 0.046. R, = 0.059. Further details of the crystal