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The significance of fermi resonance for the collisions of triatomic molecules with atoms

โœ Scribed by D.C. Clary

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
401 KB
Volume
74
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Quantum cakulatlons of vibrational excnatlon cross sections u(u -v ) are reported for the three-dlmenslonal colhslons of Hc atoms w ~th OCS and CO1 (I(U -v')/u' plots obramed from calculations usmg harmomc molecular potentlals show some osctiatmg structure When rcahstlc anharmomc potentlals are used. thts structure remxms for OCS but IS removed by strong Fermi resonance effects in CO2

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