Influence of Fermi resonance on the rotational constants of linear triatomic molecules
β Scribed by M.H Andrade e Silva; G Amat
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- English
- Weight
- 931 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0022-2852
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π SIMILAR VOLUMES
Quantum cakulatlons of vibrational excnatlon cross sections u(u -v ) are reported for the three-dlmenslonal colhslons of Hc atoms w ~th OCS and CO1 (I(U -v')/u' plots obramed from calculations usmg harmomc molecular potentlals show some osctiatmg structure When rcahstlc anharmomc potentlals are used
Methods for calculating the rotational constants of floppy triatomic molecules and atom-linear molecule complexes are discussed. It is shown that previously published equations relating the rotational constants to expectation values of moments of inertia correspond to an approximate separation of ro
Even when a simple valence force field is used to represent the bound state normal modes, the kinetic energy operator couples bending and stretching motions in bent triatomic molecules. These bend-stretch couplings have been ignored in previous theoretical descriptions of photodissociation and are s