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The Shielding of Crystal Field at Tm2+ in CaF2

✍ Scribed by Anisimov, F. ;Vala, A. ;Dagys, R.

Publisher
John Wiley and Sons
Year
1971
Tongue
English
Weight
130 KB
Volume
6
Category
Article
ISSN
0031-8965

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πŸ“œ SIMILAR VOLUMES

Crystal Field in CaF2:Tm III
Crystal Field in CaF2:Tm III
✍ F. Anisimov; R. Rakauskas; R. Dagys πŸ“‚ Article πŸ“… 1969 πŸ› John Wiley and Sons 🌐 English βš– 117 KB
Overlap and covalent contributions to th
Overlap and covalent contributions to the crystal field splittings in CaF2:Tm2+
✍ F. Anisimov; R. Dagys πŸ“‚ Article πŸ“… 1971 πŸ› John Wiley and Sons 🌐 English βš– 395 KB

## Abstract The crystal field splittings in CaF~2~:Tm^2+^ were calculated within the framework of the complex (TmF~8~)^6βˆ’^. By separating the overlap from covalent contributions, the overlap effects were found to dominate. It is shown that ligand‐ligand overlap effects are important. On the contrar