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Crystal Field in CaF2:Tm III

✍ Scribed by F. Anisimov; R. Rakauskas; R. Dagys


Publisher
John Wiley and Sons
Year
1969
Tongue
English
Weight
117 KB
Volume
35
Category
Article
ISSN
0370-1972

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Overlap and covalent contributions to th
✍ F. Anisimov; R. Dagys πŸ“‚ Article πŸ“… 1971 πŸ› John Wiley and Sons 🌐 English βš– 395 KB

## Abstract The crystal field splittings in CaF~2~:Tm^2+^ were calculated within the framework of the complex (TmF~8~)^6βˆ’^. By separating the overlap from covalent contributions, the overlap effects were found to dominate. It is shown that ligand‐ligand overlap effects are important. On the contrar