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The SF5Ox Radicals, x=0–3

✍ Scribed by Marc Kronberg; Stefan von Ahsen; Helge Willner; Joseph S. Francisco


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
118 KB
Volume
44
Category
Article
ISSN
0044-8249

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Unrestricted SCF h4O~caIcuI~tions in the INDO approximation lead to.a satisfactory explanation for the absence. of a detectable hyperfine interaction between the unpaired electron and the unique-rgFnudeus of tile radical SF,. They thus support the reassignment of an EPR spectrum that was first attr

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## Abstract UV spectra of SF~5~ and SF~5~O~2~ radicals in the gas phase at 295 K have been quantified using a pulse radiolysis UV absorption technique. The absorption spectrum of SF~5~ was quantified from 220 to 240 nm. The absorption cross section at 220 nm was (5.5 ± 1.7) × 10^−19^ cm^2^. When SF

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I'be polycrystalline ESR spectrum of the SF5 radical has been observed in y-irradiated sulphur hesafluoride at -196' after annealïng the sample at -137' to remove the SF6 radical which is also produced by the ïrradiation. A satisfactory simulation of the highly anisotropic powder spectrum was achiev