The Setting Behaviour of α- and β-CaSO4 · 0,5 H2O as a Function of Crystal Structure and Morphology
✍ Scribed by S. Follner; A. Wolter; A. Preusser; S. Indris; C. Silber; H. Follner
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 479 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0232-1300
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The novel thioantimonate(III) [Fe(C 4 H 13 N 3 ) 2 ]Sb 6 S 10 • 0.5 H 2 O was synthesised under mild hydrothermal conditions by allowing elemental Fe, Sb, and S to react in a 50% diethylenetriamine (dien) solution. The compound crystallises in the monoclinic space group C2/c with a = 33.789(3), b =
Crystal packing of the studied compounds pSUp (a) and pSEp (b) drawn with the CERIUS 3.1 software package [17] . Unit cells and hydrogen bonds are indicated with dashed lines.
Hybrid density functional theory calculations on the structures, vibrational frequencies, electron binding and dissociation energies, and bonding properties of CuO - 3 and CuO 3 species have been carried out. Stable isomers containing an O 3 subunit and composed of O 2 bound to CuO have been located