𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The Selectivity Principle and the Question of the Bridged Structure of the 2-norbornyl Cation

✍ Scribed by Herbert C. Brown and Edward N. Peters

Book ID
123651806
Publisher
National Academy of Sciences
Year
1974
Tongue
English
Weight
376 KB
Volume
71
Category
Article
ISSN
0027-8424

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Inductivity and bridging in the formatio
Inductivity and bridging in the formation of 2-norbornyl cations
✍ Cyril A. Grob; Pawel Sawlewicz πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 French βš– 199 KB

The effects of substituents at C5, C6 and C7 on the solvolysis rates of 2-norbornyl p-toluene sulfonates confirm that through space induction is directional and depends on distance and bridging strain.

The Norbornyl Cation: Prototype of a 1,3
The Norbornyl Cation: Prototype of a 1,3-Bridged Carbocation
✍ Prof. Dr. Cyril A. Grob πŸ“‚ Article πŸ“… 1982 πŸ› John Wiley and Sons 🌐 English βš– 928 KB

## Abstract The protracted discussion of whether 2‐norbornyl cations are bridged or unbridged, __i.e.__ nonclassical or classical, has lost most of its meaning, because these terms apply to the extremes of a graded series of structures. This is shown by a study of the solvolysis of stereoisomeric 6