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The Nature of the 7-Norbornyl Cation and its Rearrangement into the 2-Norbornyl Cation

✍ Scribed by Stefan Sieber; Prof. Dr. Paul von Ragué Schleyer; Dr. Hrvoj Vančik; Dipl.-Chem. Milan Mesić; Prof. Dr. Dionis E. Sunko

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
329 KB
Volume
32
Category
Article
ISSN
0044-8249

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The syn dimer of cyclobutadiene (tricyclo[4.2.0.0(2.5)]octa-3,7-diene, TOD) is subjected to ionization under different conditions and the resulting species are probed by optical and ESR spectroscopy. By means of quantum chemical modelling of the potential energy surfaces and the optical spectra, it