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The selective homogeneous hydrogenation of alkynes in the presence of alkenes catalyzed by [RuH(PMe2Ph)5]PF6

✍ Scribed by Michel O. Albers; Eric Singleton; Marjorie M. Viney


Publisher
Elsevier Science
Year
1985
Weight
326 KB
Volume
30
Category
Article
ISSN
0304-5102

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✍ Bernard Demerseman; LoΓ―c Toupet πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 203 KB πŸ‘ 2 views

## Abstract The deprotonation under basic conditions of the keto‐phosphane ligand in complexes {Ru(Cp)[Ξ·^1^‐__P__‐Ph~2~PCH~2~C(=O)__t__Bu](PPh~3~)(L)}[PF~6~] (L = CO or PMe~3~) that arise from the addition of L to {Ru(Cp)[Ξ·^2^‐__P__,__O__‐Ph~2~PCH~2~C(__t__Bu)=O](PPh~3~)}[PF~6~] generates {Ru^+^(Cp