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Hydrogen transfer processes in the formation of cationic η5 -dienyl complexes of ruthenium(II): X-ray structure of [Ru(1-5-η-cyclooctadienyl)(PMe2Ph)3][PF6]

✍ Scribed by Terence V. Ashworth; Anthony A. Chalmers; David C. Liles; Elsie Meintjies; Hester E. Oosthuizen; Eric Singleton

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
290 KB
Volume
284
Category
Article
ISSN
0022-328X

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Comparative chemistry of μ-η1 : η2-allen
Comparative chemistry of μ-η1 : η2-allenyl and μ-η1 : η2-acetylide complexes: η5-cyclopentadienyl complexes via alkyne-allenyl coupling in the reactions of PhCCPh with [Ru2(CO 6{μ-η1 : ηβ, γ2-C(Ph)CCH2}(μ-PPh2)] and [Ru2(CO) 6{μ-η1 : η2-CCPh}(μ-PPh2]. X-ray structures of [{Ru2(CO) 4{μ-η2(C,O),η5-C5MePh2(C6H4)(O)}(μ-PPh2)}2] and [Ru2(CO) 5{μ-η2(C,O), η5-C5HPh2(C6H4) (O)}(μ-PPh2)]
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