The Second-Order Doppler Displacement of the Mössbauer γ-Radiation in Amorphous Solid States
✍ Scribed by A. I. Tugushi; L. O. Tkeshelashvili; L. Zh. Zakharov
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 122 KB
- Volume
- 209
- Category
- Article
- ISSN
- 0370-1972
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✦ Synopsis
The influence of two-level tunnelling systems and bosonic peakº on the second-order Doppler displacement of Mo È ssbauer g-radiation in disordered materials is investigated. It is shown, that the Mo È ssbauer frequency temperature displacement at temperatures 10 À4 K `T `wm " hak B is determined by bosonic peakº and at T `10 À4 K by two-level tunnelling systems.
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57Fe-MSssbauer emission spectra of 57Co-labelled [Co(NH&] 2(C204)3-4H,O and [Co&&] ,(C,O,),-9H,O show an increased yield of 57Fe(Il) species. The stabilization of ferrous 57Fe species is attributed to the consequences of an autoradiolytic process involving oxdate anions in the se&d coordination sphe