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The Rotational Spectrum of Isobutane up to 640 GHz: Splitting of the |K| = 3 Transitions

โœ Scribed by D. Priem; J.-M. Colmont; D. Petitprez; S. Bailleux


Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
142 KB
Volume
184
Category
Article
ISSN
0022-2852

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๐Ÿ“œ SIMILAR VOLUMES


The Millimeter- and Submillimeter-Wave R
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The ground state rotational spectrum of \(\mathrm{CH}_{3} \mathrm{CF}_{3}\) was measured from \(190 \mathrm{GHz}, J=18\), up to \(910 \mathrm{GHz}, J=87\) and \(K=63\). These measurements allow us to determine accurate molecular constants, including the three sextic centrifugal distortion constants:

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The milimeter-wave, submillimeter-wave, and FIR spectra of the ground state of \(\mathrm{CHF}_{3}\) have been observed and analyzed up to \(J=78\). The resulting spectroscopic constants are: \(B_{0} / \mathrm{MHz}=\) \(10348.8706(2), D_{j} / \mathrm{kHz}=11.34482(13), D_{J K} / \mathrm{kHz}=-18.1176

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A comprehensive reinvestigation of the rotational spectrum of pyrimidine was carried out by using several different spectrometers. All singly substituted 13 C-and 15 N-isotopic species of pyrimidine have been measured in natural abundance with millimeter-wave free jet and waveguide Fourier transform